We need more information. The basic answer is this: You need enough fittings to join your hoses to your cooling blocks, pumps, res, radiator, and any other components. Beyond that, 1 or 2 T fittings are recommended, and finally a T-Line Cap for each T-Line you choose to use.
Hopefully all of your components will come with the necessary fittings, but I'm assuming you're asking this because you're wanting to build it all yourself. Design first, ask us for our opinions to see if you forgot anything, then purchase components. It'll go much more smoothly.
Also, I would highly recommend brass fittings for all of the waterblocks and radiator(s). Plastic fittings are usually good for the pump, as the pump housing is plastic and brass barbs are really good for cracking them. Plastic Y's and T's are just fine, since they will see virtually no stress.
When I say plastic, I'm usually recommending Nylon. Hope this helps.