Microsoft Netmeeting. It comes bundled with Windows 2000 and Windows XP. Type in an IP and if the person on the other end has Netmeeting, it will pop up and ask you if you wanna chat. Just make sure the recieving end of the call isn't behind a router as it's near impossible for Netmeeting to find the computer past a router (hence the router is doing it's job ).
In XP just do a search for Netmeeting.
In 2000 it's in your start menu under Accessories -> Communication.
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