As stated above, actual flowrate and what a pump is rated for are two very different things.
IF you had a system that actually ran at 400 gph it would perform somewhat better than a system that ran at 100 gph; exactly how much better and cooler it would run I cannot say. But it would.
I have an example of the same thing myself, due to two different pumps:
Eheim 1048- about 150 gph. I needed this pump for another system
MaxiJet (forget model)- about 300 gph. New "upgrade" pump.
Temps with the MaxiJet (rated at TWICE the flowrate) were the same as with the Eheim. The MaxiJet lasted about 3 months and started leaking everywhere.
The Eheim may have been rated for less, but due to its other technical specs and its design, was a better pump and actually pushed about the same flowrate through the system.
I do not have a Little Giant pump, but I do know a bit about them, and they are VERY strong pumps!! Much more likely to actually get near their rated flowrate than most of the ones used in watercooling- including Eheims, Hydors and Danner Mag pumps.