Mine does the same thing, temps went down 2C after a week.
I think the silicone tubing "leaks" alcohol fumes. But, on the good side, the system is sterilized before it's gone (mine's airtight), so no buggies grow in it even after months of 24/7 runtime.
I'd say around 5% or less as for the mix. I used more at first, and my tubing got a white residue...who knows what from.