It could be two (relativly) simple problems- either something isnt plugged in right (like memory or your PSU plug) or something is grounding itself... try taking EVERYTHING out of the case- place them on a table and connect the basics (power, video, CPU, HS/f, Memory) and boot up- if it posts then its probably grounding or shorting itself on the case- a solution is to use paper/thin card washers on the mobo.
if there is no sign of booting (just a brief flash, a small moment of your HS/f whirring) then take off the memory and try again... if still no luck then try without the video card.
I had that problem about a month ago- turns out my memory had popped out of the Dimm slightly and was easily solved>> just put it in again and cursed it to hell and back.
If you can... try with a different Power supply too (suddenly thought- it may be a dodgy PSU or one that's underpowered for your system)