Newbie looking for help and advise!!??

I've been studying overclocking for some time now, but am brand new to the game. Before I start, I would really like to hear from any of you guys with experience on this setup:
ASUS P4G8X
INTEL 2.66 P4
2x512 KINGSTON PC2700, DDR, ECC Memory
ASUS V9180/TD/N/64m/A Video
CREATIVE 'SOUNDBLASTER LIVE' 5.1 Sound
2x80 Gb HDD
Samsung 48x CD/RW w/DVD Rom
PLEXTOR 48x CD/RW

Any advise would be greatly appreciated,

Dobro