Doesn't matter the MB so much, more so the CPUs.
XP Pro supports 2 CPUs (2 physical and 2 virtual)
2k Pro does the same, and as you move up the ladder, it supports more.
Not sure on Win2003, but I know they all support 2. Some even more. Data center supports more than any of us can afford.
Only 64 bit CPUs are the Opts and Nocans. 2k3 and XP 64 should work on both.