The APP version includes openCL, which you don't need for starcraft.
It could speed up other applications which can use hardware acceleration in compute intensive tasks - opencl in regards to graphics cards is used for gpu compute operations. Its used for things like multimedia work and could be used in encoding/decoding stuff to speed things up. Its similar in nature to directcompute or cuda if you are familiar with either of those.
http://en.wikipedia.org/wiki/OpenCL
The APP version, I believe, includes everything the other version does, and an additional <10MB of stuff for the OpenCL thing.