If you have good airflow in the case (like at least AIO on top, next to RAM), then you can try 1.45-1.50V. RAM may lose stability at higher temps, starting from ~62-66°C+ (depending on the frequency and some other things), so if it crashes in any test, then check if it wasn't too hot before you start adjusting timings or other things. I don't remember how it was with this G.Skill kit, but V-Color with the same IC runs in my small ITX box at 66-68°C 24/7 for maybe 2 months. It seems too hot, but somehow it works without errors.
Keep hwinfo64 in the background, as it remembers all the sensors and works much better than any motherboard software.
I was checking Gigabyte Z790 AORUS Elite AX with Hynix M-die (like in this G.Skill kit) up to DDR5-7200+, but it wasn't easy to stabilize. I recommend checking something around DDR5-6800 CL32-40-40 lower tRFC, 480-560, tREFI to the max (I don't remember how much this motherboard had). It should work at 1.45-1.50V. If you notice any instability or that RAM is too hot, then try CL34 at a lower voltage.
In this generation, focus on frequency and later play with timings.
On your cooler, 13700K should run at 5.5-5.6GHz on all cores, but the motherboard sets weird voltages, so you have to play with settings to have stable ~1.35V (maybe less, depending on the CPU). At 1.4V+ it will overheat in long CPU stability tests but will probably run fine in games.
The latest BIOS is adding a 6GHz option, and it works fine, but expect it's like default/auto settings with a single-core turbo up to 6GHz, so overall performance is not much different.