G 1/4" is a BSPP thread, at 19 threads per inch. NPSM has nothing to do with these fittings or blocks. You will occasionally see G 1/4" listed as G 1/4" BSPP.
Again, with the compression fitting, just toss a second o-ring on there to make sure it seals well with the GTZ. (there's a collar around the existing o-ring that will hit the black cover on the block, a second allows it to make full contact and compress, sealing the connection)