Other then the usual you have,-
(CPU load line calibration) That calibrates the vCore, when the CPU is stressed it increases the vCore to compensate for vDroop.
(CPU NB load line calibration) as above but with the NB
(CPU current compatibility) I don't know exactly but i think this controls the voltage stability on the mosfet side, again when stressed it gives it extra volts.
(CPU current compatibility) same, this time for the CPU's DRAM controller
(CPU voltage frequency) you can set a pre programmed vCore depending on what speed you have the FSB set at.....
There are endless settings options, it looks like far to many and that its over complicated.
But actually its simply that every conceivable aspect available for overclocking and in that to fine tune to absolute stability at the best thermal solution is there.
Once you start playing with it and then test to see the results of messing about in HWMonitor it all starts to make sense and fall into place.
For example if your overclock is perfectly stable at lower vCore at idle then set those lower volts by using the (Manual Mode) on the CPU & NB Volts option instead of the (offset increase) in the BIOS.
And then use the (CPU load line calibration) setting to boost the vCore once the CPU is loaded up.
My CPU is completely stable at idle @ 1.36v, under stress it needs 1.38v, so i set it (Manual mode) 1.36v and then the (CPU load line calibration) to ultra to compensate for the vDroop and also push it to 1.38v when it needs it, it works remarkably well...
I tested it in HWMonitor, it idles at around 1.36v when stressed it climbs to 1.38v and holds it there..
You can do this for the mosfets, the RAM controller, the FSB, the NB............
You have to play with it a lot to see how it behaves and then use the settings to change that behaviour to get it to behave how you want it to.