haynes manuals usually have wiring diagrams with colors of wires, or if you buy a harness intended to plug into factory harness and connecting aftermarket stereo, you could work backwards from that, it's wires should be labeled. should be able to find one at wal-mart for less than $15, at least the last one I got was less than 15.
the computer psu should work fine, i've done it, and any modern psu should handle a stock radio just fine. in the bedroom i've been running an alpine head on a stock dell psu out of a P4 with no problems, except the stereo needs to be connected to the molex before turning on the psu, otherwise the inrush current from charging the capacitors in the stereo trips the psu's overcurrent protection, but if its all connected before powering on the psu all is fine.