I just looked at memory pricing at one major UK supplier checking out 3 DDR5 speed grades and one DDR4 for indication.
Kit, lowest £ kit, and £/GB
DDR5-5200
2x16 118 3.69
2x24 176 3.67
2x32 210 3.28
DDR5-5600
2x16 125 3.91
2x24 188 3.92
2x32 225 3.52
DDR5-6000
2x16 130 4.06
2x32 288 4.50
DDR4-3600
2x8 43 2.69
2x16 78 2.44
2x32 177 2.77
So it looks like the 24GB modules are at price per capacity relative to 16GB modules. At the lower speeds 32GB is slightly cheaper per capacity, but at the higher speed it seems to cost more.
I've still not gone DDR5 yet as my existing systems are not hurting enough for me to build new, but it would be disappointing if 32GB modules go single rank already. The extra performance from dual rank is not something I want to lose, and the alternative going "2 DPC" has a rather severe clock penalty on DDR5. I only just upgraded my DDR4 laptop from 1Rx16 to 2Rx8 after finally finding some, as most were 1Rx8 now. Prime95 surprised me at over 100% speed benefit in memory bound loads, with most other workloads being more modest at lower tens of %. This is with both running dual channel at JEDEC 3200. I found and ordered some desktop 1Rx16 just to see how bad it is under better controlled testing than is possible on a laptop.