It is very, actually the most insignificant gains in overclocking, to overclock the RAM. Your performance increase would be in the single digit percentile numbers, the biggest "improvement" in purely synthetic loads like crushing pi decimals. That being said, if you like crushing pi decimals and want to be 1,2% faster than you were, sure get fast RAM, otherwise don't bother, unless your CPU overclocking is bottlenecked by the RAM that is.
AFAIK the FX-series is quite easy to overclock a bit being multiplier unlocked, so it shouldn't be much of an issue. Just don't buy anything slower than 1600 so the other pair shouldn't bottleneck your 1866 too much.