No reason to paint the inside, like inside rad fins. I'd take a old toothbrush and a bit of dish soap to it. Heck do it to all the bits. No reason to rinse in distilled. Just take all the brass etc bits, clean well, run water through rads and blocks etc. Don't forget the rad dance, and pour scalding hot sink water over all of them to kinda sterilize. Then a rinse in distilled.
Well, that's kinda what I did. On first builds and rebuilds.