AS3 requires a minimum of 72 hours before it reaches its optimum performance. In many cases, the compound will not be at its best until several hundred hours have elapsed. Pressure on the thermal joint and the vibration of the fan facilitates the break-in. Since a water based system will only have a small amount of vibration from the case fans, the break-in period can last much longer than with air cooling. Some people with water-cooled systems report that their temperatures did not reach their lowest point for several months.
Also, running a program that stresses the CPU has no effect on the break-in time. The additional 10C or so higher temperature at the thermal joint will not shorten the break-in period. The relevant factors are pressure and vibration, not temperature.
The computer does not have to stay on throughout the break-in period. With an air-cooled system, the compound will take 3 days to 8 days to break-in if you leave your computer on all the time. If you only turn on the computer for 1 hour per day, the compound would take 72 days to 200 days to break-in.
We have been tempted to mix up a special short-term silver compound for reviewers to use for testing heatsinks so that they do not have to wait for the AS3 to break-in. We have prototypes here that beat AS3 by 3 or 4 degrees on a hot processor when first applied, but then the AS3 catches up with the prototype in a week or so. A month or so later, temperatures with the AS3 are lower than the short-term use prototype as the performance of the prototype begins to deteriorate.
Ultimately, we believe that long-term performance and stability is much more important that how the compound works fresh out of the tube, hence the break-in period.
Nevin House
Arctic Silver, Inc.