ASUS Crosshair III = much older 7xx series chipset.
870 Extreme3 R2.0 = uses a newer 8xx series chipset although not the top of the line chipset like the CH3 did in its' heyday.
I would think the later chipet would do better with a later Phenom 2 type cpu than the CH3 might. But it really is a tossup if you are going to use a Phenom 2 cpu.
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