Im gonna get crapped on for suggesting this...
The rampage iv has "oc settings" built in. Go through your bios, and make a good mental note of stock settings, and then enable the "gamer oc setting". Go through again and note what changed, including VID/Vcore (my asrock is stupid and calls vcore "vid", and vid "input voltage", not sure what the rampage does for this); multipliers, etc. Please note, this is just a very quick way to get started, not your be all, end all solution.
2 things -> output wattage (heat) is directly proportional to frequency and exponentially proporition to voltage. So fight the gut reaction to "add voltage" wantonly. Doing the quick overclock is not a gaurantee of system stability, and in all likelyhood, probably over volted pretty badly.
So start off at the settings, run some benchmarks for 10-20 minutes; noting temperatures. Some cowboys run 85+, but I really strive to stay below 80c during stress testing. Die degredation is partially to blame by heat, so keep temps cool, and you're good to go. BE VERY MINDFUL of your temps on your first runs... it might spike pretty quickly. So, if your temps are great at that voltage and frequency; you have two options. Go UP in frequency, or go DOWN in vcore. If youre content with 4.5ghz, lower the voltage until you get instability, then slowly creep up until you hit your sweet spot. On the flip side, you can grind out a raise in frequency to where its stable.
OR -
On the flip side, set stock voltage, and add multi until it crashes; and thats typically considered your "oc margin". Add a bit of voltage; rinse and repeat. Pretty simple process
Lastly,
theres a wall with every chip. For example. mine is 4.8ghz on my 4790k. 4.0-4.7 all runs pretty smoothly under 1.28v. 4.8ghz requires 1.4+v (I honestly didnt even try to get it stable; took 1.4v to BOOT, and thats not really worth my time). Small gains for an massive jump in vcore required. I usually find the wall, then subtract one, find my voltage and add a sliver more. Has worked well for me. I.e. my 4790k @ 4.7ghz appears "stable" at 1.265v, but I bumped it up to 1.280v. The differences are negligible temp wise and haven't had any issues at all (that said, Im probably going to be delidding).
Sorry for the wall, hope this helps in some way.