well first off make sure you have a good CPU cooler. To be honest, I haven't seen a whole lot of 65-nm core 2 duos make that large of a jump (increase clock speed by 1 gig Hz) on air-cooling alone. Btw, why is your 2.66 stock speed rated at only 2.0?
To make a nice jump like that, you're going to have to increase core voltage up a bunch, at least to 1.3, probably 1.4, maybe a touch higher (personally, the closer i get to approaching 1.5 volts, the more i poop my pants).
Also, for me, it never hurts to have some RAM with some headroom that can allow for some linkage, I've experienced better OC results overclockable RAM