There is another way, without using extensions.
Get 12v 12v relay from radio shack or any auto parts store (used for fog lights), connect the switched leads to the green and black wires fron the secondary psu's atx plug. Then power the other two leads with any molex 12v (butcher a fan connector for readymade harness).
When the primary psu comes on, it will turn on the relay which effectively attaches the green to black of the secondary psu, turning it on. The devices attached to it will provide the load.
You can also use this psu to power other things like cd drives, lights etc to save the primary psu for the motherboard and main harddrive only...more power available for that monster overclock.
The extension way is nice, but I don't like the power loss from the connector the psu comes with, let alone using double connectors on the power line.
I'm just cranky that way 8)