Temps still seem high to me for that cooler and CPU (although I the last time I used an H100 series cooler was on the 980x @ 4.2GHz and under load with LinX it hit 65c). I would check the lines between the rad and the pump to make sure nothing is kinked to inhibit flow. I would also make sure sure it is seated flat. Perhaps thats the temps for those CPUs though?
EDIT: I have found a review of that cooler. It was tested with a 4770k @ 4.2GHz and temps topped out at 80c with the AIDA64 FPU test. Given that the 4770k runs hotter than yours, I would definitely say there could be a performance or installation problem.
2nd EDIT: Going back to your screenshot of prime95 with coretemp, you can see a 10c difference in temps between the cores. Again, not having any XP with these CPUs I am only guessing, but that looks like something with the installation is amiss. Anyone with 4770k XP want to weigh in on that?