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On X299 you may need different settings and voltages. It's already good you can make it work at 4000. This memory is designed for 2 channel platforms. Check profiles if you have them in BIOS. It's Mem Try It or something similar.
It also depends on the IMC. My 7900X ends on ~4100 even though motherboard is rated at 4200 using Skylake-X. Looks like on your first screenshot memory was on 2 channels only, even though you see 32GB. If there are some errors then motherboard is disabling channels but will still show full capacity. I have only 2 sticks so can't even check on my X299 how it works.
woooow, nice job man! i couldnt wait for the new amd gear to come out so i bought a 8086k and msi z370 gaming pro carbon to tide me over. got sweet deals on both woot woot i cant friggin wait to play with them along with this memory!
Did you get your Kingston 4000Mhz memory working with Z370 Pro Carbon?
Could you share your settings for that memory, I'm still having stability issues.