That's correct, the 85 was on the "hotter" CPU. Apparently one chip tends to run ~10-12c hotter than the other. But what I meant was, Two Rads, then to the motherboard block, 1st cpu block, 2nd cpu block, then the OTHER motherboard block(this one is small and simple, but still another block). Not to mention the tubing for that area has some tight bends so that might be adding to it. I'm fine with what I can do with it, since the voltage I used to hit 85c was more than i'd like, and didn't really get me much OC at all.
I just wanted to see if I could improve it a bit. Especially since the GPU loop is working extremely well, I figured it wouldn't even care with part of the mobo block added to it.