Looks like when you changed it to 1866, your mobo changed the timings to 9-11-11-28 (and I'm guessing 2T - can't see the bottom part of the app for the "Memory" tab in CPU-Z). I'm guessing it will be stable there, but I'm thinking you can get better timings than that out of that RAM.
Go back into BIOS under OC Tweaker > DRAM Configuration.
There should be tCL, tRCD, tRP, tRAS, and command rate (CR). They'll be set to 9-11-11-28 and 2 (or 2T), respectively. Change them to 9-9-9-24 and 2 (your default ram timings). Try to boot and run Prime or memtest86+. If your system doesn't boot, you'll have to either increase timings or increase voltage.
Two things, by the way.
1) I would recommend overclocking CPU first if you'll be doing both. It's easier to find the max stable speed of your CPU with your RAM at stock speed. Takes a variable out of the stability equation and even if you end up not being able to OC your RAM at all after you OC your CPU, you will still see more improvement from CPU OC than from RAM OC.
2) Regardless of which you do first, I would run some benchmarks at stock speeds and then at each "max" OC you find. With these, you can compare later and see what the best option will be (higher ram speed vs lower timings).
You're on the right track. Keep having fun.
P.S. Just that first screen shot is necessary. The "SPD" tab in CPU-Z just shows defaults for your mobo/ram, not current settings.