52c load for a Phenom II X4 @ 4 GHz at 1.49v is perfectly reasonable. Furthermore, he should be safe in 60-65c range even, unless he isn't able to maintain stability.
He can lock his CPU again and measure the difference between the motherboard sensor and the CPU sensors, but generally they will read the same thing +/- 5c.
I did try extensively to figure out the difference in socket and core temps. I had a thread running with results about a year ago. In my case its about 8 degree. I mean socket runs about 8 degree higher than CPU cores. But the problem is wattage, which is I am not comfortable with. CPUZ shows 160 and HWMonitor shows 167. MY MB can accept CPU upto 140W, so I am already on or beyond boarderline.
And I know software reporting of Wattage cou;ld be very off, but I don't want to catch fire either.
If he were at 60c right now, there still would be no problem. You have to remember, some CPUs run hotter than others, and others are more leaky than others.
I had a CPU once that with a 4 heatpipe HDT cooler (Sunbeam Core Freezer) and 3800 RPM fan would load to 56c at 3.9 GHz / 3 GHz CPU-NB - with 1.52v/1.35v, what it needed for that clock.
I've got another that goes all day at 4 GHz / 2.8 GHz with 1.37v / 1.25v, running 46-48c load on a Corsair H70.